Have to admit that my own perception of issues with alloy steel use are incorrect to a certain extent, 5160 and 52100 are the real performers among alloy steels that harden enough for blades. 5160 and 52100 are both consistenly rated pretty high, they easy outperform 4140 and most all other alloy steel. The general reccomendations to use simple carbon 10xx steels is almost always linked to those starting out in making. 10xx steels are way easier to sharpen and file profile/grind so this makes a lot of sense. Have to admit that due to my own interest in both experimenting with materials and high impact choppers and axes I hope to acquire some of the seldom used alloys and see what happens. Looking at the charts I am picking out 4150, 8650, 8660, 9260, and in tool steels A3 looks very interesting compared to A2, .2% more carbon, less manganese (decreased forgeability?), big increase in vanadium to .8% up to 1.4%, equal toughness and even higher wear resistance. Given Gough's tests with A2 coming out on top easy this makes A3 interesting to me.
So far as alloy steels go I do not have a clue if, for instance, 9260 silicon Mn steel is foregeable or worksble at all, might be hot-hard or totally useless for any blade related purposes, still curious anyway.
So far as carbide formation question goes, maybe eutectic zone or "peaks" would better describe the general concept I am trying to ask about, just wondering in general about potential changes from alloy elements in the band or zone wherein carbides would begin to form due to the inability of the Fe matrix to hold any more carbon in solution when hardened under standard(ish) conditions.