Robert,
S5
Carbon 0.60%
Manganese 0.90
Silicon 1.90
Chromium 0.20
Molybdenum 1.30
Vanadium 0.30
Preheat 1200 F./ 650 C.
Hardening (145 deg. F. oil quench) 1725 F. / 940 C.
Temper before steel cools to below 125 F.
As quenched - 61 Rc
300 F. / 150 C. - 60
400 F. / 205 C. - 59
600 F. /315 C. - 57
800 F. / 425 C. - 52
S7
Carbon 0.50%
Manganese 0.70
Silicon 0.30
Chromium 3.25
Molybdenum 1.40
Vanadium 0.25
Same heat treat temps as S5 *EXCEPT S7 IS AIR QUENCHED* - temper before steel becomes less than 125 F.
As quenched - 62 Rc
300 F. - 59
400 F. - 58
600 F. - 55
800 F. - 52
I do not have temper times but you can not temper tool steels too long, only not long enough. I would go three at 2 hours per with a preceeding snap at about 50 degrees F. less.
My written source, Heat Treatment, Selection, And Application Of Tool Steels by Bill Bryson, says of S7: "Its best working range is ontained by tempering at 450 F (230 C.), which produces a 58 Rc hardness".
Tempering between 500 and 700 F. can/will cause brittleness.
Roger