I'll merge the two threads. No need to have two threads on the same issues.
Stainless steel has two things happening in HT. One is the carbon-iron structure changing phase into austenite and then converting back into martensite or pearlite. This happens around 1450-1500°F. With high alloy content, this will happen to some degree even in air cooling. To fully HT stainless steel, it has to be taken through the phase change and then to the solution point of the alloying - around 1900-2000°F. Since the alloying is often as high as 20-40% of the steel, this makes a big difference. Without the right process ending in the high temperature step, the carbon may end up improperly distributed between the carbide formers and the iron, resulting in a poor or useless blade.
As to cryo:
When the steel has high alloying, the tendency for retained austenite after quench is increased. The martensitic finish point (Mf) is also much lower. In stainless steels, the Mf is around -100°F. The cryo or sub-zero treatment allows the steel to finish the conversion to martensite. It also allows some changes in the type of carbides formed. It results in a harder and tougher steel matrix. Almost all high alloy and stainless steels benefit from cryo.
Cryo/sub-zero is part of the cooling curve of the quench. It should be done in a more-or-less continuous drop. Done a day later it will get poor results. Done a year later it will get no results. The RA will be long stabilized by then.
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