There are basically 2 ways of doing it.
As Trippyr says, one way (the cheapest) is to remove the guards, run a suitably-sized drill (usually 1/2", but maybe something else-it depends on the grinder spindle) through the centre of the buffing wheel and mount it instead of the stone. Sometimes you'll find the washers on your grinder are stepped and will not accommodate the thickness needed for a buffing wheel. Large diameter flat washers of the right ID will usually fix this.
The other way is to buy pigtail adapters to screw onto the spindle; you'll need to make sure you get the correct theads. Bear in mind that one end has a left-handed thread.
The first method makes it a pain to change mops, but keeps the loads in close to the bearings. The second method makes changing mops easy, but gives a lot of overhang. Neither is ideal. I went the first route myself, since I'd not be particularly comfortable adding pigtails and overhang to a cheap grinder, built down to a price, with already-marginal bearings. If I used a buffer much, I'd spend the money on something designed for the job.