properties of abrasives described

zyhano

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Hi boys and girls,

when talking about sharpening there is always a need to classify what the abrasives on the sharpening medium is so we have a way of comparing the different sharpening tools by different manufacturers out there.
In this post I will explain what abrasives are, what makes them a good abrasive, where you should use them and how we should describe them.


what are the factors for a good abrasive?

Particle size or particle size distribution (the average size) is an important part of the equation to get an edge that is worth calling sharp. It is important for the working speed of the abrasive and for the amount of metal that will be removed (at the scale of the abrasive). Larger particles will remove larger pieces of metal than smaller particles. The size of the particles will be an average size mostly, since this is a difficult factor to control (within limits) but the deviation of this average is what makes a stone of high quality or not. A large deviation from the average means the quality is low and this will have the effect of the abrasive seeming to be of a larger particle size, as the larger particles have a larger effect on the abrasion process.


The shape of the abrasive is also important. Particles which are angular will be more agressive and faster cutters than rounded particles. Sharp and angular corners are better and faster metal rippers than rounded and soft shapes. This is a characteristic that differs for natural occuring stones, waterstones, ceramics and diamonds. This is also one of the criteria that can play a role in your selection of sharpening tools.


The hardness of the abrasive, most often expressed in the Mohs scale (there are others), is important because there must be a hardness difference between the abrasive and the thing it is abrading.
The new Mohs scale of mineral hardness rates diamond at 15 whereas the old one (mostly used) rates diamond at 10. Talc is rated at 1. It's all about resistance to scratching. Steel is rated between 4 and 8, dependent on the steel properties and the hardening of it. A material that scratches more easily than another (lower Mohs value) can be scratched/abraded by that other material. That is the whole principle as to why sharpening and the longevity of the sharpening medium works. More information can be found here: http://en.wikipedia.org/wiki/Mohs_scale_of_mineral_hardness
The Mohs scale is not a linear scale and not consistent but provides an order in which we can place materials. Other scales exist for specific types of hardness measured, for us knife nuts the Rockwel Scale is also a thing that is well known (C variety: HRc, see http://en.wikipedia.org/wiki/Rockwell_scale)

Toughness is also a part of the equation. Particles need to be able to withstand shock or they can break in the process of sharpening. This will reduce the particle size, lessening the effect of the abrasive (making it in essence a finer abrasive). Toughness, or the lack thereof, can influence the effective lifetime of the abrasive.


There are two more factors that are not an intrinsic property of the abrasive material itself.

The bond between the abrasive particles. Particles adhere to each other or to a medium (like diamond in nickel) that keeps them in place. If the bond is too strong, the surface will become smooth over time (because of toughness and fracturing occuring) and abrasion rate will suffer from this. If particles do not adhere well, the abrasives will be ripped out and the stone will wear and lose shape. This is what happens to natural stones and why they need to be lapped. So lapping is a process that is both used to keep stones in shape with a bond that is too strong (ceramic, see http://en.wikipedia.org/wiki/Ceramic) and for stones with a bond that is not strong enough (waterstones, to get the stones level/flat). Diamond stones are embedded in nickel in a thin coating. Therefore, when pressing down with metal on diamond stones, the diamond abrasive particles can be ripped from the nickel medium which is essentially a weak bonding agent. Since it is only a thin layer of diamond, they can be easily ruined by using too much pressure. Done right, the diamond surface can last a long time.

The distribution density of abrasives might be considered too since this will effect the speed and ease of sharpening. As an example, one abrasive particle on a piece of glass will take you a loooong time to get something sharp. On the other hand, a lot of abrasive particles together have a pronounced effect on the speed.


All these factors come together in different materials that can be used for a sharpening tool. But materials are not the factor of a good abrasive, they are the medium that contain a useful mix of the properties mentioned above.



What materials are often used?

Different materials are used for different purposes. When going through the sharpening process there are multiple stages you can go through and different materials will be used. Grinding, polishing, sharpening and lapping are terms that define stages. Grinding is the bulk removal of metal and creating the shape and setting the edge, sharpening is what I consider the overall process, polishing is extremely refining the edge and lapping is for flatness. You can look up more about these processes here: http://en.wikipedia.org/wiki/Metalworking

Natural occuring materials were the first to be used in sharpening and are all crystals with some useful material properties as described above.

Quartz crystal is 7 on the old Mohs scale and is about as hard as hard steel. It is not sufficient for modern super steels which have higher hardness and crazy compositions. It is used in sandstones and comes in all sizes and often bonded because of a natural proces involving calcite.
Novaculite crystal (http://en.wikipedia.org/wiki/Novaculite) is found in the arkansas stones. The particles are highly regular in shape.
Aluminium Oxide is an important sharpening material.
When mixed/contaminated withabout 25% Iron Oxide and some small quantities of other materials, it is called emery.
Corundum is almost pure Aluminium Oxide. It is a better medium than emery. Problem with the natural materials emery and Corundum is that is does not have very good bonding properties.

Artifically created materials were developed which made better sharpening possible
The process of vitrification (http://en.wikipedia.org/wiki/Glass_transition) and the use of it for making a bonding agent is what made Norton a big player in the sharpening industry.
Silicon carbide (carborundum: http://en.wikipedia.org/wiki/Silicon_carbide), with an old mohs hardness of 9 to 9.5, was developed in 1891 and artificial corondum (pure aluminum oxide: http://en.wikipedia.org/wiki/Corundum), with a hardness of about 8, in 1897. Both were better sharpening materials than the available. For Aluminium Oxide, the process of crystallization could be controlled, thereby making it possible to create it in different particle sizes, which was a factor in it's succes.
Diamond (http://en.wikipedia.org/wiki/Diamond) was cost prohibitive for a long time, but since it is one of the hardest materials (but not the hardest: http://en.wikipedia.org/wiki/Carbon_nanotube), 10 on Mohs, it is potentially the best scratcher of the whole lot. Expensice diamond dust was used, but commercial succes came with new processes like crystal growing diamonds by General Electric and explosive/pressure conversion of Carbon to Diamond crystals.
Crystal generation creates monocrystalline diamonds, which is generally accepted to be much better for sharpening than polycrystalline diamonds. Monocrystalline does not fracture as easily, just like natural diamond. Polycrystalline is ideal for lapping and polishing, since it breaks down in the process because of it's aggregate nature, creating a finer abrasive while using it. Monocrystalling is more expensive but has a longer life and better performance.

There are more abrasives, but they are more exotic/expensive in nature and probably not relevant for this discussion.

When polishing with small sized particles, we see some other abrasives being used.
Diamond particles in solution, either spray or paste, are also used with small particle sizes for polishing.
Chromium Oxide (Cr2O3, http://en.wikipedia.org/wiki/Chromium(III)_oxide), also know as green compound is one of the well known, cheap and excellent materials for polishing. It has a Mohs value of about 8 to 8.5.
In essence, diamond, Al2O3, Cr2O3 are the most important polishing compounds. There are more polishing compounds but maybe others can describe them (black compound etc.). They are not as important.
Others that are sometimes mentioned and also not so important are:
IronOxide (Fe2O3, http://en.wikipedia.org/wiki/Iron(III)_oxide), also know as red rouge and rust is a fine polishing compound but only suitable for soft metals like brass and optics
Cerium Oxide (CeO2, http://en.wikipedia.org/wiki/Cerium(IV)_oxide) is sometimes mentioned but is more often used on glass.
Tin Oxide (SnO, http://en.wikipedia.org/wiki/Tin(II)_oxide) is used on soft metals.



A bond, in the broad sense of the word, often used for using polishing compounds is wood and leather (strops: http://www.bladeforums.com/forums/showthread.php?t=770338&highlight=demo+how+to+build+strop). Also, the polishing compounds like Cr2O3 can be bought in multiple forms, like in a solution, paste, wax or dry form, giving you a choice in how you apply them on leather/wood etc.

Plain (high quality) leather is said to have an effect on refining an edge, because of the small polishing silicates contained in it (smaller than 0.1 micron) and because of the way it moves over an edge, but there is no consensus on this.



where are those materials used?
diamond can be soldered into place for example in wheel dressers, pressed into the substrate, but most familiar for us is nickel plating the diamonds.
These are found on different diamond benchstones and handstones.
Examples are the dmt brand with diafolds (handheld) and duosharp benchstones, all monocrystalline (http://www.dmtsharp.com/general/whydiamond.htm)
Japanese waterstones (http://en.wikipedia.org/wiki/Japanese_waterstones) , both natural and artificial and natural stones like belgian stones, arkansas stones etc are most often in the form of benchstones.
Grinding wheels are another place where we find aluminium oxide, silicon carbide and diamond, often embedded in different subtrates. Vitrified bonds, resinoid bonds, rubber bonds and metal bonds are available.
Ceramics are usded in a lot of forms, handheld, like the doublestuff by spyderco, dc-4 by fallkniven (diamond and ceramic), spyderco sharpmaker, benchstones etc. As described above, there is little wear on these stones and they can have different abrasive particle sizes. It is a very good alround medium and is mostly corundum and carborundum based.

Sandpaper is also a very good sharpening medium, using carborundum and corundum in different particle sizes

What abrasive material should you use for a specific steel and method?
Grinding is mostly done with corundum, carborundum and diamond. It is an agressive form of removing metal so particle sizes are large
For lapping silicon carbide and aluminum oxide are used (red rouge for softer stuff)
for polishing diamond and chromium oxide are used on strops, but also very fine ceramic stones (spyderco UF etc) or very fine waterstones (japanese 8k+ stones)

In general, the harder the steel, the harder the abrasive needs to be because of a needed hardness differential. The faster you want to sharpen, the more agressive the cutter needs to be or the particles need to have a better contact with the knife (a reason that japanese waterstones are effective is because they wear, exposing fresh abrasives). The more polish you want, the finer the abrasive you need.
Diamond is sometimes preferred because it is hard and agressively shaped, more suited for modern steels.
Machining is preferred by some because it is fast and an easy way to expose a lot of particles in a short time. Since the wheels turn fast, the knife comes into contact with a lot of abrasives, since a wheel can essentially be regarded as a very long benchstone over which the knife travels very fast. Of course, this comes at the cost of more metal removal and less possibilities of fine tuning your sharpening process.
 
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Particle sizes and the scale in which to express them
An abrasive can be identified by different characteristics but important for most of us is the size of the abrasive particles and this is something we talk about often and is often a source of confusion.
How do we express this?
Mesh? Grit? microns? inches? Japenes grit or us grit or european grit?

I strongly believe in expressing this only in microns for a couple of reasons.

In essence, the metric system for sizes is logical and easily understood and easy for calculations. It is a rational international standard that is easily understood by everyone on the world, unfortunately not fully adopted by all, most notably the US and UK.
Furthermore, there is an easy nomenclature for smaller sizes in the range we measure knife related things: millimeter: 1 times 10 to the -3, 1/1000 part of a meter, micrometer (micron): 1 times 10 to the -6, 1/1000 part of a millimeter etc.

Spine thickness is measured in millimeters, blade length in centimeters, edge height in millimeters, edge width in micrometers. This is a comprehensive system.

US Mesh (http://en.wikipedia.org/wiki/Mesh_(scale)) is ambiguous, confusing and does not tell the whole story. mesh size is the number of openings per (linear) inch of mesh, so it inversely related to particle size and it is not in metric values. Essentially, all particles that fall through a mesh or sieve are of a guaranteed maximum size, but not of a guaranteed minimum size. So quality of abrasive is not stated, for example, if all diamond particles go through sieve of mesh 220 (which corresponds to 60 micron), all particles smaller than 60 micron also go through. In practice, this can be taken into consideration and complex sieves can be made, but this does not alter the fact that it is not as easily understood as particle size in micron.

European P-grade and Japanes JIS-grade suffer from the same problem and on top of that, all three are different, so there is no standard between these systems.

So please, let's all use microns. In the long run and at the moment, this is the only good and understandable option between those presented. It makes for easier communication between us and also from the industry to consumers.


Sizes of different abrasives
Almost all crystals have different sizes in which they can occur.
As previously presented, sizes are best expressed in microns.

As a reference, consider this: a very sharp and refined edge of a razor blade has an edge width of about 0.3 micron (1) and an edge height is about 2 millimeter (of course this can differ hugely depending on edge angle and blade thickness).

I will use the diamond products by dmt as an example, but keep in mind that there are tables of information comparing micron sizes with japanes waterstone grits, us grits etc. (2)

Extra Extra Coarse: 120 micron. this is 0.12 millimeter, particles can easily be seen by eye. Good for quick removal
Extra Coarse: 60 micron. 0.06 millimeter, quick removal. This is about the same as a 220 grit japanes waterstone (JIS grade)
Coarse: 45 micron. This is used for damaged edges and to restore an edge
Fine: 25 micron. To get a good shaving sharp edge. This is about the same as a 1000 grit japanes waterstone (JIS grade)
Extra Fine: 9 micron
Extra Extra Fine: 3 micron
stropping paste by dmt in 6 micron, 3 micron and 1 micron: this is for polishing an edge and getting mirror finishes

high quality chromium oxide: 0.5 micron (mirror finishes). This is about the same as a 10000 grit japanese waterstone (JIS grade)

Other diamond pastes and sprays are available at 0.5 and 0.25 micron, mostly used for straight razor sharpening. This is in the same size as the best edge width obtainable at the moment. So let that sink in for a moment. The abrasive particle is the same width as the line that joins two metal planes on opposite sides of the blade (known as the edge of course). Now that is small!

As you can see, this is an easy to understand reference to particle sizes. It's range is over almost three orders of magnitude (120 micron to about 0.25 micron) from visible particles to particles that are as large as the edge width of the knife.

for more information on how this relates to the sharpness of your knife, check this thread: http://www.bladeforums.com/forums/showthread.php?t=775392


effects of abrasives on finish
As for polishing with stones, the particles in the natural stone are rounder than grown crystals so they do not leave sharply defined geometric walls to the grooves they cut. Therefore they do not refract light very well. The very fine ceramic stones leave extremely fine grooves that will have very angular walls that refract light well. Therefore natural stones and waterstones can have a less shiny surface compared to diamonds and ceramics. The abrasive particles in natural waterstones, being softer and rounder than the grit grains in manufactured stones, have trouble abrading the various carbides in tool steel. The iron matrix is not quite as hard as the carbides it contains so the grains wear it away faster, leaving the carbides as slightly as more or less rounded domes. The matte surface is essentially a relief map of the microscopic carbides exposed during honing. The harder and sharper aluminum oxide grains in man made stones cut through the carbides as well as the surrounding matrix, leveling the surface to an optical mirror.
The abrasives are better anchored in the stone surface which allows them to shear a straight groove in the steel, carbides and all, thus creating the flatter surface.(3)

The same holds true for other polishing compounds, which is why high quality diamond compounds leave a very shiny surface.




pictures
silicon carbide crystals
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aluminium oxide crystals
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diamond crystals grown on a film
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a sharp edge with either some small parts of debris or pieces of wire edge, viewed from the top
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waterstone (left) finish compared to shapton 15k (right) finish, with right being polished in one direction. viewed from the side
Random short scratches are consistent with a surface moving over an abrasive that is free to move (i.e. a slurry of waterstone) whereas the specific direction scratches are consistent with a surface moving over a fixed abrasive (like ceramic & diamond)
attachment.php




references
1) John Verhoeven: experiments on knife sharpening.
2) Leonard Lee: the complete guide to sharpening . For this article, a lot of inspiration came from this book . I highly recommend it.
3) the sharpening blog: http://hocktools.wordpress.com/



other good stuff
on diamond growth, with pictures: http://www.chm.bris.ac.uk/pt/diamond/gustavothesis/chapter2.htm
 

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Great post, Zh! I've copied it to keep in my reference folder! Thanks for taking the time to do it all!!

Stitchawl
 
Good post, :thumbup:

Will you translate it yourself for use on the Dutch forum or shall i copy it in English ?
 
Cool thread, I was just wondering today what plain leather would rate at on the micron scale. I think I've read somewhere before that it's 0.25, but I don't recall where I read it.
 
Cool thread, I was just wondering today what plain leather would rate at on the micron scale. I think I've read somewhere before that it's 0.25, but I don't recall where I read it.

Depending upon the leather (species) the micron size can vary between .01 to .1
Horsehide has a higher concentration of silicates than cowhide. Vegetable tanned leather has a higher concentration of silicates than oil tanned or chrome tanned leather. Leather that has been properly treated for stropping (i.e. 'boned' leather) has a higher concentration of silicates on the surface of the leather than that which hasn't been boned.

The better the quality of the leather and the better the treatment of the leather for stropping, better are the results achieved from that strop. Use high quality horsehide cut from the shell or the butt of the hide, vegetable tan it, bone it well, and you'll have a strop that can't be beat!! :thumbup:

(By the way, HandAmerican sells high quality 'Horween' brand vegetable tanned horsehide cut from the butt of the hide. Horween leather is about as high in quality as is available! Not all horsehide is the same. )

Stitchawl
 
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I really appreciate members like you and your efforts. Saved for future reference, but a big help with my current benchstone quest.
 
Great post, Zh! I've copied it to keep in my reference folder! Thanks for taking the time to do it all!!

Stitchawl

Wow! Lots of good info here Zyhano. Thanks for taking the time to compile this.

Thanks guys! You're welcome
Good post, :thumbup:

Will you translate it yourself for use on the Dutch forum or shall i copy it in English ?
Tnx for asking, translating is going to be too much work. I'll put it up as is, ok?
Tnx
I really appreciate members like you and your efforts. Saved for future reference, but a big help with my current benchstone quest.
You're welcome, glad to hear it. That was actually a motivation for me to write this, since you could use this info while searching for a good stone. Once you understand the above, everybody should be able to make a better choice when getting sharpening materials.
Very cool zyhano, very much appreciated.:thumbup:
And it's appreciated that you let me know:D:thumbup:
 
Verhoeven and Lee are my primary sharpening references. I have not read Juranich's book. There is a lot of information in the Lee book, while the Verhoeven paper allows us to see what is actually happening, except with leather.

Verhoevens micrographs don't show noticable change in the edge width or surface finish of the stropped blades. There is obviously something going on, though apparently we can't see it at 3000x magnification on an electron microscope:eek:. I've seen the effects of just stropping my Cara Cara on my belt, going from hair shaving sharp to hair whittling sharp in less than 100 strokes. Maybe that little bit of burr debris left on the edge is getting cleaned off. Maybe there is some dirt or other contaminant stuck to the edge that the leather removes.

The use of the Mohs scale is a little misleading and it's not that good a comparision between the minerals (talc to diamond) it was intended for and steel. It's also not linear. There is a large difference between a 9 and a 10.
 
Verhoeven and Lee are my primary sharpening references. I have not read Juranich's book. There is a lot of information in the Lee book, while the Verhoeven paper allows us to see what is actually happening, except with leather.

Verhoevens micrographs don't show noticable change in the edge width or surface finish of the stropped blades. There is obviously something going on, though apparently we can't see it at 3000x magnification on an electron microscope:eek:. I've seen the effects of just stropping my Cara Cara on my belt, going from hair shaving sharp to hair whittling sharp in less than 100 strokes. Maybe that little bit of burr debris left on the edge is getting cleaned off. Maybe there is some dirt or other contaminant stuck to the edge that the leather removes.

The use of the Mohs scale is a little misleading and it's not that good a comparision between the minerals (talc to diamond) it was intended for and steel. It's also not linear. There is a large difference between a 9 and a 10.
yes, both are amazing sources of information. For those who don't know, you can download the article of verhoeven as a pdf online, just do a google search. There are some good explanations in there, good theories, good experiments and good pictures.

Lee is an excellent book, describing a lot about sharpening different tools but also how cutting works.

Jurianich is informative, but I like Lee better. I feel Jurianich's book was good for the time, but is a little bit outdated with the coming of newer steels and technologies/discoveries
Just another thank you! Nice job!
thanks, You're welcome!
 
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