there are several ways to harden leather though all are variants of the same concept.
the first, and foremost rule is that the leather must be vegetable tanned. If you'regetting your leather from a regular leather dealer they will be able to tell you, but the "regular" leather from tandy is veg tanned.
in armour making, the term for hardened leather is courbouilli, which translates to boiled leather in french.(so I've been told) most leather workers discourage putting the leather in boiling water.
so those who work with hot water typically keep the water at 180 degree. dip the leathere till it reaches it's plastic state and form it to the shape you want. This can be done with forms(known as lasts) or freeform.
The way I have used with good results involve soaking the leather till it becomes pliable, then form it to the desired shape and place it on a wood dish in an over setto 180 degrees and check it every 15 minutes or so. The leather will swell a bit and become hard, almost to the point of wood.
other leather workers will add a glue(typically titebond 3 or elmers) to the water to further increase the hardness. I've never done that, so can't recommend one way or the other.
the other method uses molten wax to harden the leather, though for shealth work this may be counterproductive(wax being a lubricant making the leather easier to cut)
once hardened, the leather can the be treated with a water proofer.
I hope this helps
kindyr