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Because first temper cycle make some correction in steel from quenching .And second temper make some correction in steel from first temper cycle .You don t need to know what is going on inside steel , just follow instruction for HT protocol and you are goodI understand how the tempering temperature effects final steel hardness but the tempering time itself - does that really matter? why do we do 2 hors and not one or three for example?
I’d think most carbon steels are going to be closer to 60RC at a 400F temper. 26C3 is the only steel I’d be close to 63RC at a 400F temper. I quench for 10s in parks 50 followed by quench plates. So far my hardness results have matched up (+-1pt) with the appendix in knife engineering. For example all the 52100 I just did was at 62RC after a 350F temper. I think lower tempers than 400F have their place especially with kitchen knives.I have seen people suggest lowering the second temper, but there is no realistic advantage to it.
The first temper sets the hardness pretty much. The second only coverts the new martensite, which is a very small percentage. The second temper does not appreciably lower the hardness from what it was after the first unless it is done at a higher temperature. On that subject, I see people suggesting tempers at 350°F and such. A temper below 400°F for most normal steels and normal use knives is not needed. At 400°F the hardness is still in the Rc63-64 area for most simple carbon steel. Raising it to 425°F only lowers the hardness about 1 point. You have to get to 500°F to drop below Rc60.
All this is based on a proper and complete quench. If you are not getting the desired hardness results, the likely culprit is that you did not fully harden the blade.
This requires the right temperature and soak time for the austenitization, the right quenchant type t the right temperature, and the right rate of cooling after the quench. While we all love to see the guys on FIF pull the blade right out of the quench and have it burst into flames ... which they blow on to extinguish ... THIS IS NOTA GOOD QUENCH PROCEDURE!!!
Quench into the proper oil and hold in the oil ( moving up and down) for 8 to 10 seconds before removing. Then let cool at a normal rate hanging in the air until you can pick it up by hand ( a magnet bar is great for this). If using quench plates, place the blade in the plates and leave for at least a couple minutes. Doing a proper quench will give a hardness of Rc 66-65 on most simple carbon steels. Tempering at 400°F will drop that 2 to 3 points.
I’d think most carbon steels are going to be closer to 60RC at a 400F temper. 26C3 is the only steel I’d be close to 63RC at a 400F temper. I quench for 10s in parks 50 followed by quench plates. So far my hardness results have matched up (+-1pt) with the appendix in knife engineering. For example all the 52100 I just did was at 62RC after a 350F temper. I think lower tempers than 400F have their place especially with kitchen knives.
I would take that result with grain of salt not as 100% accurate or as rule .... On other equipment someone will get other result ............I was working out of memory.
I'll just took a look at Larrin's charts. I was thinking the other simple steels (1095, 1084, W2, Hitachi W/B, 23C3), were around Rc62-63 at 400F like 26C3was. I see that some drop to Rc61 and one closer to Rc60 at 400.