Yes Bambooleaf, I agree with you. There are exceptions to every rule. One can always paint himself into a corner when trying to talk in absolutes. All your examples are good ones. At one time each one was the hight of technology. But one could counter argue that flint and chert benifit from heat treatment and were heat treated in their time periods with a sort of annealing process that makes it easier to work. Copper bronze and brass work in the opposite way that carbon steel does. Hammering work hardens it. To soften it to prevent it from cracking from over working you heat it to cherry red, then quench it. The hammering of the bronze is what transformed them into a usable spearpoint or sword. Bone can be hardened by slow roasting near a fire and even wooden tip spears were hardened in the fire. Obsidian may be as close to an out the box material as you could get, but even it was heat treated in nature by being melted and slow cooled as to retain its ideal properties.
The point I was trying to make, altho perhaps poorly, is that it is the heat treatment that makes a knife, a knife.
Lets use a file as an example.
The difference between a file and a knife is in the heat treatment. To make a file, you take a bar of 1095. Cut the teeth into it, heat to critical and quench. This makes a very good file with a rockwell hardness of 62-65. Keep that file cool and grind an edge on it put on a handle. It looks like a knife, but is actually a very poor one and close to useless. It is almost immpossible to sharpen and is very brittle. Any amount of flex and it will break like a piece of glass.Chopping with it will chip out the edge. Because this file has been made into the shape of a knife, does that mean it is a knife? I really don't think so. Altho the shape and look is there, it fails at the tasks we call on a knife to do.
Now if you take another piece of 1095,or even that file, grind it to the shape of a knife, heat it to critical, quench, then put it in the oven and draw the hardness back to 58-60 rockwell and put on a handle. Now we can sharpen it easily. It is hard, but not too hard. We can chop and flex the knife without fear of it breaking or chipping out on the edge. It performs all the tasks we call on a knife to do. It is now a knife.
I don't think it is unreasonable for me to want my throwing knife to perform with the qualities I feel are important in a throwing knife.
1. It won't break easily.
2. It won't bend easily
3. It will hold its tip well, but not chip out.
This ideal is easily achieved by my choice of steel and method of heat treatment. I can choose either to learn to do it myself, or buy one from someone that understands the qualities needed, and how to bring them out and make a piece of steel into a knife.