I have used Dexter-Russell Hi Carbon boning knives (models 1375, 1376, 1377, and 1378) at work on both party/charter fishing boats and commercial fishing boats for over 13 years. They begin to attain a patina after the first day of use. A fresh water rinse after use in the beginning keeps them from rusting until a dark patina has eventually formed. after a couple months, the freshwater rinse is often neglected, (I've NEVER oiled the blade of a carbon steel knife by the way) yet
minimal amounts of rust form. if you never rinse the knife with freshwater in the beginning, a patina forms, but so does brown rust, and eventually there is nothing you can do to prevent it BUT oil the blade. we cut fish that are a. taken home by the people who caught them, or b. sold at market. Oiling the blade with synthetic oils is not an option. I have heard of guys keeping 12 oz water bottles with the tops cut off full of olive oil or other type of cooking oil to put the knives in, but this only works if the bottle is secured from tipping and only with the shorter bladed 5 and 6 inch "rippers". I never tried the man made patina in those days because I did not know about it.
However in my experience
thus far (perhaps I should have clarified this earlier) I have experienced little to no rust on carbon steel blades that have been allowed to form a patina naturally, and more rust on knife blades that have had a patina applied rapidly and not under natural circumstances.
As for the "scientific" basis of my idea, I am a scientist, but my field is fisheries, not metallurgy.
Unlike most "scientists" however, I take more stock in experience than in "theories" and "hypothesis."
Again, what I have posted here is from
my own experience. YMMV
as Jack Palance used to say: "Believe it...or not."
Pete