You can make a better "guess" if you can see the entire spark stream. Looking at the burst, by themselves, is not as informative. I like to spark test in a dark room using a big cup stone on a grinder to produce the sparks. Put comparitive samples in the vise and grind them, switching one from the other. I've been fooled on more than one occasion.
I have a spark test book, with nothing but pics in it of different metals being tested; it gives an idea of what it might be, but I think it takes a lot of experience to make a positive identification. You can learn a lot more with carbon steels by testing them as quenched.