Well, I tell ya. I'v switched to teflon washers in all my knives due to similar observations. I used to use nothing but PB washers in all my custom folders and rebuilds. Here in the last year I've had a few come back to me for other work. One was a custom I did about two years ago. The customer decided he wanted a low rider pocket clip on it now and it didn't have a clip at all before. I got it took the clip side scale off and got inside the folder as I normally would to do a clip for tip up right hand carry and the pivot looked horrible. I didn't document that one, just cleaned it up and did the work sending it home. Then it happened again with other knives.
Recently I got a Stretch in that I redid in titanium liners, PB washers, and of course reused the original blade. He wanted new handle scales on it to replace the old Micarta ones I did. Here is what I saw when I got inside it in these two pictures. This knife was used for food prep, rinsed under the sink, and treated as it had always been treated. It didn't show this the last time I took it apart when it was still the factory set up and had no washers.
Alls I can figure is that its some kind of beginning stages of galvanic corrosion taking place. The other thing I now know is that by replacing the washers with Teflon the problem goes away. I have four knives I know of now that I've replaced the washers in and kept up with over time. None have had this reoccur after replacing the PB washers with Teflon washers.
So, what does this mean? Well, sometimes you have to go where the facts lead you I guess. I'm not saying I know for sure but for me the path of least resistance and the easiest cure was swapping the washers. It seems to me PB washers are no good on kitchen use, food prep use, tactical or outdoors folders or survival folding knives. I'd measure the washers thickness using a good digital caliper and find some the same thickness from Texas Knifemaker supply, Jantz supply, Knife and Gun finishing supply, or Sheffield supply that will fit your pivot diameter and swap them if you are seeing this in your folders. Its cheap and easy to do.
STR