I know you make knives. Part of what I do is I help people choose an appropriate analysis technique and to assess analytical results to assure the results meet the needs of the person using those results to make decisions.
The XRF compares its measurements to the partial set of elemental specs for 440C that it can quantitate. If the C was 0.5% it wouldn’t be 440C but that XRF won’t know it and will still tell you it is 440C. Since your analysis didn’t cover C did you really have sufficient data to decide it was 440C? Maybe, it depends upon how sure you need to be. C should be 0.9-1.2 in 440C per ASTM A276.
The XRF states V is 0.18, but there is no spec for V in 440c. I think some cutlers like V in their steel and would be happy to have it.
The Cr at 16.1 is just within the spec of 16-18. Do some cutlers like Cr to be on the high end of that range? For Cr with the 2std of the results being 0.3, there is an ~5% chance Cr could be as low as 15.7. To be sure 95% sure it meets spec, one would prefer the Cr to be 16.3.